hantzsch reaction using [mesi]cl as a new, efficient and bail catalyst

نویسندگان

sami sajjadifar

hamid saeidian

sayeh zare

hojat veisi

sobahn rezayati

چکیده

in this work, the efficiency, generality and applicability of new bronsted acidic ionic liquid (bail) 1-methyl-3-(2-(sulfooxy)ethyl)-1h-imidazol-3-ium chloride {[msei]cl} as heterogeneous and green catalyst for organic transformations are studied. herein, the following one-pot multi-component reactions in the presence of [msei]cl are investigated: (i) the synthesis of quinoxaline derivatives from the reaction of phenylenediamines and 1,2-diketones in etoh under mild conditions (room temper-ature), (ii) the preparation of 1,4-dihydropyridines from one-pot multi component condensation of 1,3-dicarbonyl compounds, nh4oacand aldehydes under solvent-free conditions at moderate temperature (90 °c). high yields, relatively short reaction times, efficiency, generality, clean process, simple methodology, low cost, easy work-up, ease of preparation and regeneration of the catalyst and green conditions (in the synthesis of the quinoxaline derivatives) are advantages of the application of [mesi]cl as catalyst in the above organic reactions.

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Hantzsch reaction using [Mesi]Cl as a new, efficient and BAIL catalyst

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عنوان ژورنال:
iranian chemical communication

ناشر: payame noor university (pnu)

ISSN 2423-4958

دوره 1

شماره Issue 1 (pp. 1-82) 2013

کلمات کلیدی
[ ' h a n t z s c h r e a c t i o n ' , ' q u i n o x a l i n e s y n t h e s i s ' , 1 , ' m e t h y l ' , 3 , ' ( 2 ' , ' ( s u l f o o x y ) e t h y l ) ' , ' 1 h ' , ' i m i d a z o l ' , 3 , ' i u m c h l o r i d e { [ m s e i ] c l } ' , ' s o l i d a c i d ' , ' i o n i c l i q u i d ' , ' g r e e n c h e m i s t r y ' ]

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